Interesting, I think the Canon TC is very much like a powermate in that it should be vastly superior to any barlow lens, I do not know however if using one without a lens would produce an error code (easy to try out), I have found this old thread that may help.
This is something I must try myself with my Kenko version .
I think the method of connection is to fit the TC to the camera as normal then use a EOS to T adapter fitting into the Teleconvertor you then would need the standard kit for fitting into the focus tube etc, you will need a two inch extension in there too.
Alan