Looking at your RELCO spectrum on your blog here https://roslistonastronomy.uk/wp-content/uploads/2018/09/CCDSPEC-RELCO-Spectrum-130918e-Image.bmp It looks like you have some problem with ghost spectra at the blue end which could make it difficult to indentify lines.  Your spectrum should be cleaner than this, more like this spectrum taken with my ALPY